Q: Why do stars change in their outward properties (L, Ts, R), as they mature as a main sequence stars and then age toward their demise as giant and supergiant stars?

The short answer is that because changes (whether gradual shrinking or contraction) in a star's core where fusion is occuring (or perhaps no longer occuring!) must result in changes throughout the rest of the star, including its surface.

A little more information....

So what's happening in the hydrogen fusing core of a main sequence star?

Well, 4 hydrogen nuclei are being fused into a single helium nucleus many times per second (emphasis on many), releasing energy that ends up replacing that energy lost at the surface of star we call star light - luckily, there are a lot of hydrogen nuclei available for fusion....But what impact does that have? There are two that we've discussed.

1) Gas pressure depends upon number density of gas particles exerting the pressure and the temperature of the gas. If every time a helium nucleus is formed, 4 hydrogen nuclei (and additionally 2 electrons) disappear, then gradually the number density of gas particles will drop and unless something happens gas pressure within the core will fall out of equilibrium with gravity.

2) Over substantial fractions of the main sequence life span, the "fuel" hydrogen is being converted to helium within the star's core, and helium doesn't (yet) contribute any energy from fusion to the star. i.e., the fuel tank will eventually run dry. When that occurs, relatively rapid changes will ensue.

So what's a star's core to do?

First things, first - the star's core must deal with the pressure-gravity problem. Gravity gets a slight advantage as the number of particles there drops due to fusion, and very gradually the core shrinks*. That is, gravity does work on the core, heating it - gravitational potential energy is converted into thermal energy of the gas as it shrinks. Another way to think of it is this: the smaller the core becomes, the stronger gravity becomes (masses are closer together), and so to get back into pressure-gravity equilibrium the core's gas pressure exerted must be even higher than before. With a (slightly) higher temperature (recall that Pgas is proportional to n x T, where n is the number density of gas particles and T is the temperature), the greater pressure is again able to balance the stronger gravity. But the process of fusion continually albeit gradually reduces the number of particles within the core, and so this very gradual core shrinkage is inevitable.

But wait a minute, higher temperatures in the core mean that more energy is released from hydrogen fusion...Generally speaking, that extra energy generated by the core translates into (1) making the star's envelope larger and cooler and (2) raising the star's surface luminosity (other subtle effects may play a role and can alter the outcome in detail, but we won't pay any attention to these). Why does (1) occur? Because when you dump energy into a normal gas (in this case the star's envelope), the pressure that gas exerts increases. In very small, gradual steps gas pressure in the envelope exceeds gravity, and so the envelope expands very gradually - reacting to the gradual increase in energy dumped into it from the core below. By doing work against gravity, the envelope (and so the surface) ultimately cools to re-establish pressure-gravity balance. But keep in mind that these changes are relatively minor while the star is on the main sequence; much larger changes are in store as its core runs out of hydrogen "fuel".

A general rule of thumb is that as the core becomes smaller and hotter, the envelope becomes larger and cooler (and vice versa!), for reasons just discussed. And so generally speaking, stars evolve from the main sequence over toward the upper right quadrant of the H-R diagram, eventually becoming giant or supergiant stars. As stars age away from the main sequence, their cores continue to fuse lighter elements into heavier ones (releasing energy), first within a central core, then in a shell surrounding that central core. The "ashes" of one fusion stage become the "fuel" for the next stage, assuming a sufficiently high temperature is attained to allow fusion to occur (recall that heavier elements have more protons and so are more repulsive to each other due to the electromagnetic force). While the central core is contracting, because it hasn't yet reached a sufficiently high temperature to begin the next stage of fusion, the resulting changes are relatively rapid. But after fusion begins again in the central core, the changes are much more subtle and over relatively longer spans of time. Each successive stage of central core fusion has a shorter duration than the previous one, mainly because the net energy released per full reaction becomes less and less as the heavier elements are fused.

Here are the major stages of central core fusion, with their major products, their "ignition temperatures", and the approximate minimum mass star that will go through that stage of fusion:
4H --> He;  about 10 million K; 0.08Msun
3He --> Carbon (C), then He + C --> O (oxygen); 100 million K; 0.5Msun or so
Carbon fusion: Neon, Magnesium; 600 million K or so; about 6Msun
Oxygen fusion: Silicon, Sulfur; 1 billion K or so; 8Msun
Silicon fusion: Iron; 3 billion K; 10Msun

What determines whether or not the ever-heavier elements that are produced in one stage will fuse in next stage? It is a race between density and temperature in a core that becomes ever smaller under the force of gravity. For if gravity can compress the core to become sufficiently hot to fuse that next element, it will do so and that next stage of fusion will occur. But if the core becomes too dense before the "ignition" temperature for that element is reached, another source of pressure will step in and halt the core's contraction. In that event, the core can become no hotter, and so the next stage in fusion cannot occur, signaling the end of the star's life. What is this source of pressure that occurs at very high densities?

Electron Degeneracy Pressure. This exotic form of pressure generated by the free electrons will begin to dominate over normal gas pressure in stellar interiors when the densities exceed1 10,000 g/cm3  (recall that water has a density of 1 in these units).  This pressure has nothing to do with the fact that electrons have like charges, but rather it becomes important when electrons are confined to lie very near to one another and yet are compelled to avoid one another (this same property explains why/how electrons that are bound to atoms arrange themselves in "orbital" shells). Electron degeneracy pressure depends on the electron number density (as n5/3), and does not depend on the temperature of the gas. Once established, this pressure will eventually halt any gravitational contraction2. Why is this important? Because if the electrons in a star's core become degenerate before the "ignition" temperature of the next stage of fusion is reached, that next stage of fusion will never begin, and the star will soon die, ultimately ejecting its envelope in a planetary nebula with the core (supported by electron degeneracy pressure) becoming a white dwarf. It is also this pressure that sets in to keep objects less massive than 8% of the Sun's mass from ever becoming stars, since their cores will then never become hot enough to sustain full hydrogen fusion.

Finally, consider stars with masses exceeding 10 times the mass of our Sun. They are able to fuse elements all the way up through iron, with a series of successive shells (or zones) of lighter element fusion surrounding an iron core (like layers in an onion). Once an iron core forms, catastrophic doom awaits that star - for fusion involving iron removes energy from the environment. What happens next can be summed up in this way. The above fact combined with the extreme conditions of temperature (billions Kelvin) and density ultimately result in a complete gravitational collapse of the iron core. For a variety of reasons3, the increasing temperature and density actually push pressure further away from its required equilibrium with gravity to prevent a collapse. The net result is that in a fraction of 1 second of time, an iron core about the size of the Earth and a bit over 1 solar mass collapses to a ball of neutrons about the size of Kalamazoo. The rest of the core (fusing the lighter elements in successive shells) also begins falling inward, although the star's envelope remains totally oblivious to what's happening inside. Neutron degeneracy pressure4  suddenly halts the collapse of the innermost neutron core, which then rebounds a bit like a suddenly released compressed rubber ball, sending out a shock wave that plows through the surrounding zones where fusion is still occuring. The shock wave compresses and heats these zones, the energy released from fusion becomes explosive and the star suddenly explodes as a supernova -  the star's envelope is driven away at thousands of km/s (how this happens in detail is an active area of research). At peak luminosity, a supernova emits several to 10 billion solar luminosities of light, and then slowly fades with time. Ultimately, the luminous and the kinetic energies of the exploding star, plus the energy carried away by the zillions of neutrinos formed in the explosive fusion reactions is paid by the gravitational potential energy released in the collapse of the iron core. What remains of the collapsed core is expected to be a neutron star, as long as its mass lies below 2-3 solar masses. Neutron stars are indeed observed in the centers of violently expanding supernova gas shells.

*This shrinking of the star's core converting hydrogen into helium is much more gradual than gravitational contraction, the latter eventually taking place when hydrogen is exhausted in the central-most region of the core composed of helium.
More precisely, this critical density depends upon the temperature of the gas, proportional to (T/108)3/2.
2More precisely, this pressure can support at most about 1.4 solar masses of material, depending on its composition and other details, called the Chandrasekhar limit. More massive objects initially supported by this pressure must collapse under gravity.
3Details, details...As the temperature exceeds several billion Kelvin, Wien's law of thermal radiators (blackbodies) tell us that energetic gamma rays are numerous, and some of these have sufficient energies to break apart the iron nuclei all the way back down to protons. This process removes energy from the core (it's essentially fusion run in reverse!), robbing the iron core of pressure needed to support itself. Soon thereafter the extreme densities and temperatures now present allow the free electrons to begin combining with protons to create neutrons, robbing the iron core of virtually all remaining pressure support. Very rapid ("free fall") collapse ensues - with the matter reaching infall velocities of up to 70,000 km/s! As usual, don't worry about the details.
4Neutron degeneracy pressure is similar in nature to electron degeneracy pressure, except it involves the much more massive neutron and so is much more powerful. It too has a limiting mass it can support, lying somewhere between 2-3 solar masses. The reason for the uncertainty is because inside a neutron star the densities soar to such high values (greater than 100 million - 1 billion tons per cm3) that the neutrons themselves "fall apart" (or rather this matter changes phase, as ice melts to liquid water), and we don't yet understand the nature of this form of matter. Neutron stars more massive than this limit must collapse, and the result is probably a black hole - something  so dense that light cannot escape from it...

Kirk Korista
Professor of Astronomy
Department of Physics
Western Michigan University